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Ⅰ AbstractIn portable electronic devices such as mobile phones, notebook computers, and small video cameras, lithium-ion batteries have developed rapidly due to their sound performance, such as high working voltage, large specific energy, long cycle life, low self-discharge rate, no memory effect and so on, which are compared with traditional NiCd batteries and NiMH batteries.Figure 1. Lithium-ion Movement in Li-ion BatteryCatalogⅠ AbstractⅡ Charging Characteristics of Lithium BatteriesⅢ Performance Description of Several Different Charging States3.1 On Standby3.2 Precharging3.3 Constant Current3.4 Constant VoltageⅣ Charging Process Analysis4.1 High Voltage Constant Current Mode4.2 Low Voltage High Current Mode4.3 High Voltage High Current ModeⅤ Li-ion Battery Charging Security5.1 Common Sense in the Daily Use of Batteries5.2 Charging RulesⅥ One Question Related to Lithium-ion Battery and Going Further6.1 Question6.2 AnswerThe charge and discharge of lithium-ion batteries do not transfer electrons through traditional methods, but energy changes occur through the entry and exit of lithium ions in the crystals of layered materials. Under normal charge and discharge conditions, the in and out of lithium ions cause changes in the interlayer spacing, but will not cause damage to the crystal structure, so lithium-ion batteries can be regarded as an ideal reversible battery. During charging and discharging, lithium ions come and go between the positive and negative electrodes of the battery, and they shake between the positive and negative electrodes like a rocking chair.Lithium-ion Battery Charging BasicCharging batteries is common for people's daily life, as we all know, Li-ion batteries play a very important role in our social life with their excellent performance, in order to get longest service life, proper charging of Li-ion batteries is essential. Li-ion battery charging mode is voltage limit and constant current, which is controlled by IC chip. The typical charging method is: detect the voltage of the battery to be charged firstly, if its voltage is lower than 3V, pre-charge is required necessarily, and the the charging current is 1 ≤ 10 of the set current. After the voltage rises to 3V, then transferring into the standard charging process. The standard charging process is: having constant current charging with set current. When the battery voltage rises to 4.20V, it is changed to constant voltage charging mode, and the charging voltage is kept at 4.20V. At this time, the charging current gradually decreases till the current drops to 1/10 of the set charging current, the charging ends.The charging process of a Li-ion battery can be divided into three processes: trickle charging (low voltage precharging), constant current charge, and constant voltage charge. Ⅱ Charging Characteristics of Lithium BatteriesFigure 2. Typical Charge ProfileAs can be seen from the above figure, the charging current and voltage of the lithium battery are dynamically changed, which is determined by the chemical content of the lithium battery itself. Therefore, it is necessary to configure the performance of the charging IC according to the charging characteristics of the lithium battery itself to achieve a correct, safe and efficient use of the lithium battery. The "lithium-ion battery charging current" in the daily expression is for the charging current of fast charging. As a dynamic process, the optimal charging current of the lithium battery is actually divided into three stages. Ⅲ Performance Description of Several Different Charging StatesFigure 3. Li-ion Battery Process3.1 On StandbyThe standby state is handled in the following cases:1) The input voltage is lower than the minimum operating voltage of the circuit.2) After the battery voltage is approach to the limit.3) Using external switch to turn offmanagement IC to stop charge.Voltage and current characteristics in standby mode: The charging IC has no charging voltage output, and the IC input current is in the uA level, which can reduce power loss. 3.2 PrechargingAs shown in above figure. Optimal current during precharging: that is, when the initial/no-load voltage of the lithium battery is lower than the prechargeing threshold, it needs a pre-charging stage. For a single lithium-ion battery, this threshold is generally 3.0V, in the phase, the precharge current is about 10% of the current in the constant current charging phase. 3.3 Constant CurrentAs shown in the figure above, when the battery voltage is greater than the preset voltage threshold and less than the maximum voltage of 4.2V, the IC will charge the battery with the maximum charging current set by the external resistor. When the battery voltage is equal to the maximum charging voltage (near 4.2V), the charge stop.The best current for constant current charging: when stay in constant current stage, the voltage gradually rises, then enter the fast charging phase. Most of the constant current charging current is set between 0.5 and 1.0C, and the best set is 0.8C, because the battery can be full charged about two hours without consider other factors. The case is a good balance between charging time and charging safety.Several problems that should be paid attention to when batteries at constant current charging:1) In this state, the IC is in the state of maximum charging current, and the loss at this time is also the largest. The linear voltage drop loss calculation is L = (Vin-Vout) × Iout, it is necessary to pay attention to the maximum operating temperature of the IC.2) The increasing temperature due to the highest charging current, the IC will automatically reduce the maximum charge current, and this is why the charging current drops during overheating. 3.4 Constant VoltageThe maximum charging voltage portion shown in the above figure, when it is detected that the battery voltage is equal to or close to the battery charging voltage, at this time, the charging mode will be stepped down with a constant charging voltage of 4.2V. When it is detected that the charging current is less than 1/10 of the maximum set current, charging will stop. Charging current during constant voltage charging: In the case of a single-cell lithium-ion battery, as the battery voltage rises to 4.2 V, the constant current charging ends and the constant voltage charging stage begins. In order to achieve the best performance, the voltage stabilizer tolerance should be better than +1%.At this stage, the voltage is keeping constant and the current is reduced, and this current reduction is a sequential decrement process. Most lithium battery protection selects 0.1C as the termination current, which means that the charging process enters the end state. Once charging is finished, the charging current drops to zero. The problem to be noted in this state is that the battery can be automatically turned off when the battery is charged to the highest setting voltage. At the same time, when the overvoltage protection of the IC is in the abnormal battery state, it can be automatically locked. Unlike nickel batteries, continuous trickle charging is not recommended. Because it will cause plate plating effect to the lithium metal, making batteries failure.The core of the best charging current of lithium battery is the current design of constant current charging. It should be emphasized that most portable lithium batteries should be designed to charge 0.5C~0.8C. For example 1400mAh capacity of iPhone battery(capacity mAh= current mA × time /h), choosing 0.7C, that is, Apple’s charging current is about 1A, so that most of the batteries between 0.5C~0.8C you can choose.When charging, the voltage of the battery should be detected first. If the voltage is lower than 3V, pre-charging should be performed first. When the charging current is 1/10 of the set current, 0.05C is selected generally. After the voltage rises to 3V, it enters the standard charging process. The standard charging process is constant current charging with set current. Till the battery voltage rises to 4.20V, it is changed to constant voltage charging, and the charging voltage is kept at 4.20V. At this time, the charging current gradually decreases, and when the current drops to 1/10 of the set charging current, the charging ends.Generally, the charging current of the lithium battery is set between 0.2C and 1C. The larger the current, the faster the charging, and the greater the heat of the battery. Moreover, when lies in excessive current charging, the capacity is not full, because the electro-chemical reaction inside the battery takes time. Ⅳ Charging Process Analysis Figure 4. Charging Characteristics of Lithium-ion Battery 4.1 High Voltage Constant Current ModeIn general, the charging process of the mobile phone is to first reduce the 220V charging voltage to the 5V charger voltage, and the 5V charger voltage reduce to the 4.2V battery voltage. During the entire charging process, if the voltage is increased, heat is generated, therefore, the charger will heat up and the phone will heat up. Moreover, the greater the power consumption, the greater the damage to the battery. 4.2 Low Voltage High Current ModeWhen the voltage is constant, the current can be increased by using a parallel circuit. Under this situation, the smaller the volume shared by each circuit after parallel shunting, each circuit has the smaller load damage, so as to the phones charging process. 4.3 High Voltage High Current ModeThis method increases the current and voltage at the same time, so that from the previous formula P=UI, we can know that this method is the best way to increase the power, but it will generate more heat when the voltage is increased. In this way, the more energy is consumed, but the voltage and current are not freely increased without limitation.The maximum charging current of a lithium battery is strictly determined by the structure of the battery. Therefore, the specifications of the lithium battery manufacturers are not consistent, some are set to 0.6C, and the highest current specification for portable lithium batteries is 1C.  Of course, the current design of pre-charging and constant voltage charging cannot be ignored. In the two processes, if the initial voltage is not lower than the pre-charging threshold of 3.0V, there is no pre-charging process. In general, there is a process to check batteries charging voltage that is beneficial to keep the long-term use of lithium batteriess.Ⅴ Li-ion Battery Charging Security5.1 Common Sense in the Daily Use of BatteriesMisunderstanding: “Battery activation”, charging for more than 12 hours in the first three times.For the “activation” problem of lithium batteries, many sayings are: charging time must be more than 12 hours, and repeat three times in order to activate the battery. This statement that “the first three charges have to be charged for more than 12 hours” is obviously a continuation of nickel batteries (such as nickel cadmium and nickel hydride), in other words, this kind of statement can be said to be misinformation of the other batteries. After a sample survey, it conformed that a considerable number of people have confused the charging methods of the two batteries. Lithium-ion battery activation does not require a special method, they will be activated naturally in the normal use.The charge and discharge characteristics of lithium and nickel batteries are very different. All the professional technical data reviewed emphasize that overcharge and overdischarge can cause huge damage to lithium batteries, especially liquid Li-ion batteries. Therefore, charging is preferably performed in accordance with standard methods, especially for ultra-long charging of more than 12 hours. For example, the charging method described in the mobile phone manual is a standard charging method suitable for the mobile phone. It is not suitable to charge for a long time, also the battery is completely dischargedand thenThe lithium battery phone or charger will automatically stop charging when the battery is fully charged. There is no so-called “turbulent” charging over 10 hours for nickel battery chargers. If the lithium battery is fully charged, it will not be charged anymore continuously.Over-time charging and power off completely will cause over-charging and over-discharging, which will cause permanent damage to the positive and negative electrodes of lithium-ion batteries. At the molecular level, over-discharge will cause the anode carbon to release lithium ions excessively causing the layer structure collapses, and overcharging will hardly plug too much lithium ions into the negative carbon structure, and some of the lithium ions will no longer be released. Regular deep charge and discharge for battery calibrationLi-ion batteries generally have a management IC and a charge control IC. The management IC has a series of registers, which contain values such as capacity, temperature, ID, state of charge, and discharge times. These values will gradually change during use, so the main function of the “The batteries should be fully charged and discharged when used once a month or so” is to correct the improper values in these registers. 5.2 Charging RulesThe following rules should be noted when charging and discharging lithium ion batteries:Figure 5. Typical Li-ion Battery Discharging DiagramCharge currentItmust limited for li-ion batteries. Typically the maximum value is 0.8C, but lower values are more usually set to give some margin. Charge temperature  Itshould be monitored. The cell or battery must not be charged when the temperature is lower than 0°C or greater than 45°C. Short circuit protectionItis required to prevent damage or explosion as a result of short circuits. Over-voltage protectionItis required to prevent a voltage that is too high being applied across the battery terminals. Over-charge protectionItis required to stop the Li-ion charging process when voltage per cell rises above 4.30 volts. Reverse polarity protectionItis needed to make sure the battery is not charged in the wrong direction as this could lead to serious damage or even explosion. Over-discharge protectionItis required to prevent the battery voltage falling below about 2.3V dependent upon the manufacturer, when battery voltage less than 2.3V will make battery damage irreversibly. Over temperature protectionIt is necessary to prevent the battery operating in a high temperature, because heating will age batteries and reduce their service life. if the temperature rises too high. Temperatures above 100°C can cause irreparable damage.Ⅵ Questions Related to Lithium-ion Batteries1. How many years does a lithium ion battery last?three yearsThe typical estimated life of a Lithium-Ion battery is about two to three years or 300 to 500 charge cycles, whichever occurs first. One charge cycle is a period of use from fully charged, to fully discharged, and fully recharged again. 2. What is the difference between a lithium battery and a lithium ion battery?Lithium batteries feature primary cell construction. This means that they are single-use—or non-rechargeable. Ion batteries, on the other hand, feature secondary cell construction. This means that they can be recharged and used over and over again. 3. Why are lithium ion batteries bad for the environment?Recycling Lithium-IonUnwanted MP3 players and laptops often end up in landfills, where metals from the electrodes and ionic fluids from the electrolyte can leak into the environment. Because lithium cathodes degrade over time, they cannot be placed into new batteries. 4. Is there a better battery than lithium ion?Zinc-air batteries can be considered superior to lithium-ion, because they don't catch fire. The only problem is they rely on expensive components to work. 5. What is the best way to charge a lithium ion battery?Simple Guidelines for Charging Lithium-based BatteriesTurn off the device or disconnect the load on charge to allow the current to drop unhindered during saturation.Charge at a moderate temperature.Lithium-ion does not need to be fully charged; a partial charge is better.

SummaryThe process that makes gold-plated jewelry or chrome car accents is now making powerful lithium-ion batteries. It's reported in the Joural Science Advances that research at the University of Illinois, Xerion Advanced Battery Corporation and Nanjing University in China developed a method for electroplating lithium-ion battery cathodes, yielding high-quality, high-performance battery materials that could also open the door to flexible and solid-state batteries in May,2017. Paul V. Braun, a professor of materials science and engineering and director of the Frederick Seitz Materials Research Lab at Illinois said that it's an entirely new approach to manufacturing battery cathodes, which resulted in batteries with previously unobtainable forms and functionalities. Traditional Lithium-ion BatteryTraditional lithium-ion battery cathodes use lithium-containing powders formed at high temperatures. The powder is mixed with gluelike binders and other additives into a slurry, which is spread on a thin sheet of aluminum foil and dried. The slurry layer needs to be thin, so the batteries are limited in how much energy they can store. The glue also limits performance. "The glue is not active. It doesn't contribute anything to the battery, and it gets in the way of electricity flowing in the battery," said co-author Hailong Ning, the director of research and development at Xerion Advanced Battery Corporation in Champaign, a startup company co-founded by Braun. The researchers bypassed the powder and glue process altogether by directly electroplating the lithium materials onto the aluminum foil claimed "You have all this inactive material taking up space inside the battery, while the whole world is trying to get more energy and power from the battery". The Electroplated CathodeSince the electroplated cathode doesn't have any glue taking up space, it packs in 30% more energy than a conventional cathode, according to the paper. It can charge and discharge faster as well, since the current can pass directly through it and not have to navigate around the inactive glue or through the slurry's porous structure. It also has the advantage of being more stable. What's more, the electroplating process creates pure cathode materials, even from impure starting ingredients. This means that manufacturers can use materials lower in cost and quality and the end product will still be high in performance, eliminating the need to start with expensive materials already brought up to battery grade, Braun said.  "This method opens the door to flexible and three-dimensional battery cathodes, since electroplating involves dipping the substrate in a liquid bath to coat it," said co-author Huigang Zhang, a former senior scientist at Xerion who is now a professor at Nanjing University. The researchers demonstrated the technique on carbon foam, a lightweight, inexpensive material, making cathodes that were much thicker than conventional slurries. They also demonstrated it on foils and surfaces with different textures, shapes and flexibility.These designs are impossible to achieve by conventional processes,however,what's really important is that it's a high-performance material and that it's nearly solid. By using a solid electrode rather than a porous one, more energy can be stored in a given volume. One of the day, people want batteries to store a lot of energy and peple will make this thought come true. 

A New Breakthrough in Battery Technology The breakthrough comes from a team of engineers led by John Goodenough, the co-inventor of the lithium-ion battery. A new discovery has come out which could pave the way for batteries to last more, and it won’t explode. The breakthrough comes from a team of engineers led by John Goodenough, the co-inventor of the lithium-ion battery which is used to power everything from smartphones to electric cars. Led by John Goodenough and a team of engineers, the co-inventor of lithium-ion battery has made this breakthrough. The research was published in Energy and Environmental Science in December and publicized by the University of Texas last week. The research states that in the future a “solid-state” battery design could potentially hold up to three times more energy and charge faster than today’s batteries. The solid-state battery is still in the early stages of development and swaps out one of the essential parts of today’s lithium design—liquid electrolytes—for glass components. The glass electrolytes can store more energy and are much more stable since they prevent the formation of dendrites—metallic projections which grow through liquid electrolyte layers and cause short circuits and explosions. The researchers have stated that the glass electrolytes will allow them to exchange lithium for sodium, which would be cheaper and more eco-friendly option since it can be extracted from seawater. This means the batteries would not just be economical as well, but the will be more powerful than the current batteries we have today. The solid-state batteries can also work in extreme conditions, down to -4 degrees Fahrenheit. This could be a massive breakthrough for car batteries, which obviously have to work through extreme weather. This breakthrough sounds exciting—but it could still be a long way from coming to modern age smartphones. This was just preliminary research, similar to other solid state designs we have seen in the past, so there’s no timetable for when the batteries might actually be applied for practical use, if ever.As super battery started to be used in the works, lithium-ion may be history.  Super battery with supercapacitors“Super” is a popular adjective when it comes to energy storage. Supercapacitors even have it in their name. Now they supposedly make it possible to charge smartphones in seconds and power them for a week. Super! Supercapacitors are already being used in plenty of everyday things as replacements for or supplements to batteries. They power the rear lights on our bicycles when we stop, fill in for interruption-free power supplies in the event of an emergency, prevent data loss in static memories (SRAMs) and provide a brief horsepower boost and save gasoline in racecars by accumulating recovered braking energy. Unlike lithium-ion batteries, they can release and absorb a great deal of energy in a short period of time—hundreds of thousands of times with deep discharging and high currents. However, the storable charge quantity is low. That is why they are still too large and too expensive to be used in smartphone or tablets. The reason that rechargeable batteries and supercapacitors, which are also known as ultra- or double-layer capacitors, have opposing characteristics is the way they store a charge. While this happens in “sluggish” chemical processes such as oxidation, reduction and the storage of molecules or ions in batteries, when it comes to supercapacitors, it generally happens through “swift” charge separation, which is gentle on the electrodes. Ref.KY605-NH50BP-2KY605-BP33-12S-B7   

As of the model year 2017, BMZ GmbH offers a warranty of four years on e-bike batteries to the customers of the bicycle purchasing cooperative. For this purpose, BMZ and ZEG have signed a service agreement. According to the agreement, BMZ offers a warranty to the buyers of ZEG e-bikes that their batteries will have a residual capacity of more than 60% after a period of 48 months.This means, if a customer rides his e-bike for a distance of 100 kilometres today, he can still ride it for 60 kilometres under the same conditions after four years. BMZ offers a warranty of 24 months to commercial dealers.The date of purchase by the end customer is key when it comes to asserting warranty claims. Proper handling of the batteries and chargers, for which there is a 24-month warranty, is a prerequisite for granting the warranty. A comprehensive warranty agreement, which will be sent to the dealers separately, specifies all the details.BMZ and ZEG are linked by a long-standing partnership. ZEG, the Zweirad-Einkaufs-Genossenschaft eG is an association of 960 independent bicycle dealers. It offers uniquely favourable sales and purchasing opportunities and maintains business relations with all renowned brands of bicycle manufacturers. For half a century, ZEG has been synonymous with quality and reliability.Process-oriented quality management and product quality have been taking centre stage at BMZ since the company was established in 1994. It is the foundation for outstanding products and business excellence. With innovative and high-quality products, BMZ is known for maximum sustainability.Reference:1215F101215F2X21215F2X4 

Today, more and more people prefer lead crystal batteries over lead acid batteries. This is because of the unparalleled advantage that they offer in comparison. Some of them are – Longer Battery Life Acid batteries come in varied designs suitable for different applications. Some come as Cyclic Batteries which are designed to cycle, but others are so designed that that can give out high currents for short duration of time. The applications make the designs differ. A typical acid battery can charge and discharge for an average of about 300-350 cycles. In contrast, if they are replaced by lead-crystal batteries and keep the other conditions same, the output would be about 700-800 cycles. Thus lead- to crystal batteries show almost double performance and have a longer life of about 7 to 10 years which is highly cost effective and better alternative. Shelf Life Compared to acid ones, lead-crystal batteries discharge much slower when fully charged and are either stored or transported. These batteries can be immediately put to use even after as long in storage conditions as two years. They need not be charged like the acid ones require. The 2V series retains 99.9% of the capacity even though they have not been used for over 2 months. This makes the logistics much simpler as one is freed from the responsibility of cycling the batteries in stock to be charged every couple of months. The High Rate Discharge Lead crystal batteries have special technology which facilitates high-rate discharge characteristics. Compared to the acid varieties which work optimally at discharge rates of only 3C, the lead crystal battery discharge can work optimally even at discharge rates of 10C. Excellent Performance in Terms of Charge The time taken by a lead crystal battery is only 20% of the time required by the old normal lad batteries. This improves the battery efficiency and maintenance dramatically. Depth of Discharge The lead crystal battery can be easily restored to a full rated capacity with ease even after it has been discharged to 0 Volt which may not be possible with the acid ones. There is a high probability that the acid ones may die and not recover under the circumstances. Thus the usable battery capacity of a lead crystal battery is much higher. Low Temperature Resistance The crystal ones lead batteries can function to satisfaction in a temperature range of -40 to +50 degrees Celsius. They exhibit more 85 % of its rated capacity even at minus 40 degrees Celsius where the acid ones have shown a sharp decline in ability to discharge. Green Manufactured from new materials, new processes and new formulations, lead crystal batteries are more environmentally friendly and pollution free. They do not ooze mist or emit harmful gases, unlike the acid batteries.