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Perovskite Solar Cells: Construction, Working Principles and Challenges

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Overview: The article discusses the working principles, construction, and layers of the perovskite solar cells. It also highlights key challenges such as ion migration, moisture sensitivity, and toxicity affecting stability and efficiency in energy production.

 

When compared with conventional silicon solar cells, perovskite structures are revolutionary in the domain of solar technology. Many benefits, including increased efficiency over the last decade, lower cost, reduced carbon emissions during manufacturing, bandgap tunability, and unlimited energy, have enabled perovskite cells to become more popular in producing greener energy.

 

What is the more common perovskite structure?

Perovskite is the general term for any substance with a formula  . Where A is an organic or inorganic cation (MA, FA, Cs), B is a metal (Pb, Sn, Bi), and X is a halide anion (I, Br, Cl). Different perovskite structures can be created by varying the cations and anions, and their efficacy has been investigated.

 

Methyl ammonium lead iodide is the most extensively studied structure for creating the most effective perovskite structure. where

  • MA (CH3NH3+) is the A cation
  • Pb is the heavy metal, B cation
  • I is the halide anion

 

Six iodine anions surround each lead cation to form an octahedral structure, as shown in Fig. 1. Each octahedral unit cell is connected via corners to form a cuboctahedral structure where a larger methyl ammonium cation is present in the center position, as shown in Fig. 2.

 

This solar cell has a comparatively higher absorption coefficient and a direct bandgap of 1.55 eV. Additionally, their increased diffusion length allows the charge carriers to pass through the electrode for a greater distance before recombining, contributing to electricity. Due to these enhanced qualities, thin-film solar cells with comparatively less thickness than traditional bulkier silicon solar cells may now be produced with a power conversion efficiency exceeding 20%.

Figure1-Illustration of methyl ammonium lead iodide perovskite solar cell
Fig. 1: Illustration of methyl ammonium lead iodide perovskite solar cell. Source: Rakesh Kumar, Ph.D.

 

Figure2-Illustration of cuboctahedral structure perovskite solar cell

Fig. 2: Illustration of cuboctahedral structure perovskite solar cell. Source: Rakesh Kumar, Ph.D.

 

Challenges In Methyl Ammonium Lead Iodide Perovskite Cell

Even though these cells offer many benefits, they also present some challenges.

 

Ion migration: When exposed to environmental factors, the MA ion diffuses or migrates inside the crystal structure; this process is called ion migration. This phenomenon of ion migration has a significant impact on the photostability of the perovskite structure.

 

When these cells are studied in a controlled atmosphere, their efficiency is up to 20%; however, this will drop significantly to 15% when exposed to external forces.

 

Replacing MA with a larger and longer-chain cation enhances structural stability through steric hindrance, which prevents ion movement inside the crystal structure. Alternatives should also satisfy the tolerance factor to attain a stable structure.

 

The most popular substitute is formamidinium, which performs better than methyl ammonium lead iodide with a bandgap of 1.47 eV and a power conversion efficiency of 14.2%.

 

Moisture and oxygen sensitivity: Interaction with moisture and humidity eventually causes degradation due to the distortion of the crystal structure.

 

Toxicity: The Pb-based perovskite cell makes them toxic in nature. Non-lead-based perovskite cells are based on metals such as tin (Sn), germanium (Ge), and bismuth (Bi).

 

They have been researched to produce effective and non-toxic perovskite materials. Among these alternatives, Sn has performed the best, but its stability is inferior to that of lead-based structures.

 

Construction of Perovskite Solar Cell

Proper construction of these cell layers is a critical factor in improving efficiency. A light-absorbing perovskite layer is sandwiched between p- and n-type semiconductor layers in a heterostructure.

 

This lets electrons and holes be extracted selectively, enabling perovskite solar cells to work efficiently. In every structure, the energy level of each layer is seamlessly related to that of the next layer.

 

High-quality perovskite layer manufacturing is essential for perovskite solar cells with high photovoltaic conversion efficiency. Based on the placement of alternating regions of layers, there are two types: NIP and PIN The structure of the NIP and PIN is diagrammatically illustrated in Fig. 3

Figure3-Illustration of perovskite solar cell layers

Fig. 3: Illustration of perovskite solar cell layers: a) n-i-p structure; b) p-i-n structure. Source: MDPI

 

Perovskite Solar Cell Layers

The layers in high-quality perovskite solar cells are

  • A light-absorbing perovskite layer
  • An electron transport layer (ETL)
  • A hole transport layer (HTL)
  • Conductive oxide layer (anode) Indium tin oxide (ITO) / fluorine-doped tin oxide (FTO)
  • A Metal contact layer (cathode)

 

HTL and ETL transport layers can be constructed using organic and inorganic materials.

 

Electron Transport Layer

Titanium dioxide is the more widely used electron transport layer, but it has drawbacks such as ion migration that causes deterioration and the requirement for high temperatures during annealing.

 

Thus, several additional alternatives, including ZnO, CdS, and SnO2, are selected and researched. Because of its larger bandgap, lower fabrication temperature, and greater mobility, SnO2 showed increased stability and has more potential to be used as the electron transport layer.

 

Hole Transport Layer

Spiro-OMe TAD is the organic material that is employed in the HTL layer more frequently and produces higher efficiency. The more prevalent issues with this material are its high cost and active degradation, which impair perovskite cells' stability.

 

On the other hand, inorganic HTLs are affordable, easy to fabricate, and highly stable, which serve as effective alternatives. The inorganic HTL that are used most often are poly triarylamine (PTAA), copper thiocyanate (CuSCN), FDT, copper phthalocyanines (CuPc), carbon (C), copper zinc tin sulfide (CuZnSnS2), copper indium disulfide (CuInS2), nickel oxide (NiO), and much more.

 

Transparent Conductive Oxide Layer

The transparent conductive layer is the most important component of the perovskite structure because it fulfills two essential functions.

  • Transmission of incident photons towards the light absorber layer.
  • Transmission of generated electron-hole pair towards the external circuit.

 

Proper fabrication of these conductive layers and balancing transparency and conductivity are critical factors for the efficient working of the perovskite cell.

 

Working of Perovskite Solar Cell

Through the transparent conductive oxide layer, the incident photon enters the perovskite absorber layer. The incident photon creates electron-hole pairs in the absorber layer.

 

The resulting electron-hole pair is transferred to the external circuit via the hole transport layer, and the electron transport layer generates energy. In every structure, the energy level selection and band alignment of the material for each layer are seamlessly related to those of the next layer for improved efficiency.

 

To conclude, the performance of solar cells is mainly dependent on the selection of materials for each layer, and their thickness and energy levels should be optimized to facilitate the proper transmission of charge carriers in energy production.

 

Research is being conducted to develop stable perovskite solar cells that have increased efficiency and are anticipated to hit the market shortly.

 

Summarizing the Key Points

  • Perovskite solar cells offer a promising alternative to traditional silicon cells, with relatively higher efficiency and lower manufacturing costs.
  • The construction and proper selection of layers in perovskite solar cells are crucial to maximizing energy production efficiency.
  • The selection of materials, their thickness, and energy levels are critical factors in ensuring the proper transmission of charge carriers for optimal energy generation.

 

Reference

Priyanka Roy et al., “Perovskite Solar Cells: A Review of the Recent Advances,” Coatings 12, no. 8 (July 31, 2022): 1089, https://doi.org/10.3390/coatings12081089.

Mritunjaya Parashar and Anupama B. Kaul, “Methylammonium Lead Tri-Iodide Perovskite Solar Cells with Varying Equimolar Concentrations of Perovskite Precursors,” Applied Sciences 11, no. 24 (December 9, 2021): 11689, https://doi.org/10.3390/app112411689.

Rakesh Kumar, Ph.D.

Rakesh Kumar holds a Ph.D. in electrical engineering, specializing in power electronics. He is a Senior Member of the IEEE Power Electronics Society, Class of 2021. He writes high-quality, long-form technical articles for global B2B semiconductor brands. Feel free to reach out to him at rakesh.a@ieee.org! Checkout his complete portfolio @muckrack.com/rakesh-kumar-phd | @linkedin.com/in/rakesh-kumar-phd

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