Topological Materials are a Promising Material For Boosting Thermoelectric Generation Efficiency

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Author: Kynix

Published: 2018-02-03 | Last Updated: 2018-02-03

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Warm hints: The word in this article is about 1000 and the reading time is about 6 minutes.

MIT researchers found a way to triple the efficiency by using "topological" materials with special electronic properties. Although previous research has indicated that topological materials could be used to create efficient thermoelectric systems, little is known about how electrons in such topological materials can move in response to temperature differences to produce a thermoelectric effect.

Researchers not only found that they can push the boundaries of this nanostructured material in a way that makes topological materials a good thermoelectric material,more so than conventional semiconductors like silicon,but also this could be a clean-energy way to help us use a heat source to generate electricity, which will lessen our release of carbon dioxide.

News

Today, thermoelectric devices are used for relatively low-power applications, such as powering small sensors along oil pipelines, backing up batteries on space probes, and cooling minifridges.

Scientists hope to develop more efficient thermoelectric devices that will harvest heat produced as a byproduct of industrial processes and combustion engines and convert it into electricity. However, thermoelectric devices' power, or the amount of energy they can generate, is currently limited.

"We discovered that we can push the limits of this nanostructured material in a way that makes topological materials a better thermoelectric material than traditional semiconductors like silicon," says Te-Huan Liu, a postdoctoral researcher in MIT's Department of Mechanical Engineering. "In the end, this could be a clean-energy way to help us use a heat source to generate electricity, which will lessen our release of carbon dioxide," Liu added.

Liu is first author of the PNAS paper, which includes graduate students Jiawei Zhou, Zhiwei Ding, and Qichen Song; Mingda Li, assistant professor in the Department of Nuclear Science and Engineering; former graduate student Bolin Liao, now an assistant professor at the University of California at Santa Barbara; Liang Fu, the Biedenharn Associate Professor of Physics; and Gang Chen, the Soderberg Professor and head of the Department of Mechanical Engineering.

A Path Travel Freely

When a thermoelectric material is exposed to a temperature gradient — for example, one end is heated while the other is cooled — electrons begin to flow from the hot end to the cold end, resulting in an electric current.

The greater the temperature difference, the more electric current and power are made. The amount of energy that can be produced is determined by the electron transport properties of a given material.

Scientists have discovered that certain topological materials can be converted into efficient thermoelectric devices using nanostructuring, a technique used by scientists to create a material by patterning its features at the nanometer scale.

Scientists believe that the thermoelectric benefit of topological materials stems from decreased thermal conductivity in their nanostructures. However, it is uncertain how this increase in efficiency relates to the material's inherent, topological properties.

Liu and his colleagues investigated the thermoelectric efficiency of tin telluride, a topological material considered to be a strong thermoelectric material, to try to address this issue. Tin telluride electrons also have unusual properties that resemble a class of topological materials known as Dirac materials.

The researchers wanted to understand the effect of nanostructuring on the thermoelectric efficiency of tin telluride by simulating electron movement through the material. Scientists often use a calculation known as the "mean free path" to characterize electron transport. This is the average distance an electron with a given energy can freely travel within a material before being dispersed by different objects or defects in that material.

Nanostructured materials resemble a patchwork of tiny crystals, each with its own boundary, known as grain boundaries, that separates one crystal from the next. As electrons come into contact with these limits, they scatter in a variety of ways.

Electrons with long mean free paths scatter violently, similar to bullets ricocheting off a wall, whereas electrons with shorter mean free paths are much less affected.

The researchers discovered that the electron properties of tin telluride have an important effect on their mean free paths in their simulations. They plotted the spectrum of electron energies in tin telluride against the related mean free paths and discovered that the resulting graph looked very different from that of most traditional semiconductors.

In particular, for tin telluride and probably other topological materials, the findings indicate that higher-energy electrons have a shorter mean free path, while lower-energy electrons have a longer mean free path.

The researchers then investigated how these electron properties influence the thermoelectric efficiency of tin telluride by essentially summing up the thermoelectric contributions from electrons with different energies and mean free paths. It turns out that the ability of a substance to conduct electricity, or produce a flow of electrons, under a temperature gradient is largely determined by the electron energy.

They discovered that lower-energy electrons have a negative effect on the production of a voltage difference, and hence electric current. Since low-energy electrons have longer mean free paths, they can be dispersed more intensely by grain boundaries than high-energy electrons.

Size Down

Going a step further in their simulations, the team experimented with the size of individual grains of tin telluride to see whether this had some impact on the movement of electrons under a temperature gradient. They discovered that raising the diameter of an average grain to around 10 nanometers, putting its boundaries closer together, increased the contribution of higher-energy electrons.

Higher-energy electrons contribute much more to the material's electrical conduction with smaller grain sizes than lower-energy electrons because they have shorter mean free paths and are less likely to scatter against grain boundaries. As a result, a greater voltage difference can be produced. Furthermore, the researchers discovered that shrinking the average grain size of tin telluride to around 10 nanometers yielded three times the amount of electricity that the material would have produced with larger grains.

Although the findings are based on simulations, Liu claims that researchers can achieve comparable results by synthesizing tin telluride and other topological materials and changing their grain size using a nanostructuring technique.

Other researchers have proposed that shrinking the grain size of a material can improve its thermoelectric efficiency, but Liu claims that they have mostly assumed that the ideal size is much larger than 10 nanometers. "In our simulations, we discovered that we can shrink the grain size of a topological material far more than previously thought, and based on this principle, we can increase its performance," Liu says.

Tin telluride is one of the topological materials that have yet to be discovered. If researchers can determine the optimal grain size for each of these materials, topological materials, according to Liu, can soon be a viable, more effective alternative to producing renewable energy.

Conclusion

Liu believes that topological materials are excellent for thermoelectric materials, and our findings indicate that this is a very promising material for potential applications. The Solid-State Solar Thermal Energy Conversion Center, an Energy Frontier Research Center of the United States Department of Energy, and the Defense Advanced Research Projects Agency contributed to this research (DARPA).

Article From Proceedings of the National Academy of Sciences

Article Edited by kynix

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