A New Breakthrough In Organic Electronics

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Author: Kynix

Published: 2017-11-28 | Last Updated: 2017-11-28

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Summary

Published in the Joural Nature Materials in Nov.13,2017,reaearchers from Princeton University,the Georgia Institute of Technology and Humboldt Uniersity in Berlin is pointing the way to possibly more widespread use of organic electronics. Their research focuses on organic semiconductors,a class of materials prized for their applications in emerging technologies such as flexible electronics, solar energy conversion, and high-quality color displays for smartphones and televisions. In the short term, the advance should particularly help with organic light-emitting diodes that operate at high energy to emit colors such as green and blue.

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“Organic semiconductors are ideal materials for the fabrication of mechanically flexible devices with energy-saving low-temperature processes,” said Xin Lin, a doctoral student in electrical engineering at Princeton and the lead author. “One of their major disadvantages has been their relatively poor electrical conductivity. In some applications, this can lead to difficulties and inefficient devices. We are working on new ways to improve the electrical properties of these organic semiconductors.”

Semiconductors, typically made of silicon, are the foundation of modern electronics because engineers can take advantage of their unique properties to control electrical currents. Among many applications, semiconductor devices are used for computing, signal amplification and switching( signal switches ). They are used in energy-saving devices such as light-emitting diodes and devices that convert energy such as solar cells. In the doping process used to make semiconductors their chemical makeup is modified by adding a small amount of chemicals or impurities. By carefully choosing the type and amount of dopant, researchers are able to alter the electronic structure and electrical behaviour of the semiconductor in a number of ways.

As the article shows,researchers have developed an approach for greatly increasing the conductivity of organic semiconductors,which are formed of carbon-based molecules rather than silicon atoms. The dopant, a ruthenium-containing compound, is a reducing agent, which means it adds electrons to the organic semiconductor as part of the doping process. The addition of the electrons is the key to increasing the semiconductor’s conductivity. The compound belongs to a newly introduced class of dopants called dimeric organometallic dopants. Unlike many other powerful reducing agents, these dopants are stable when exposed to air but still work as strong electron donors both in solution and solid state.

Seth Marder and Stephen Barlow from the Georgia Institute of Technology, who led the development of the new dopant, called the ruthenium compound a “hyper-reducing dopant.” They said it is unusual, not only in its combination of electron donation strength and air stability, but in its ability to work with a class of organic semiconductors that have previously been very difficult to dope. In studies conducted at Princeton, the researchers found that the new dopant increased the conductivity of these semiconductors about a million times.

The ruthenium compound is a dimer, which means it consists of two identical molecules, or monomers, connected by a chemical bond. As is, the compound is relatively stable and, when added to these difficult-to-dope semiconductors, it does not react and remains in its equilibrium state. That posed a problem because to increase the conductivity of the organic semiconductor, the ruthenium dimer needs to react with the semiconductor it and then split apart.

The researchers looked for different ways to break up the ruthenium dimer and activate the doping, eventually they added energy by irradiating with ultraviolet light, which effectively excited the molecules in the semiconductor and initiated the reaction. Under exposure to the light, the dimers split into monomers, and the conductivity rose.

"Once the light is turned off, one might expect the reverse reaction to occur" and the increased conductivity to disappear, Marder said. "However, this is not the case."

The researchers found that the ruthenium monomers remained isolated in the semiconductor even though thermodynamics should return the molecules to their original configuration as dimers.

The team's hypothesis is that the monomers are scattered in the semiconductor in such a way that it is very difficult for them to return to their original configuration and re-form the ruthenium dimer. They are, according to the team “kinetically trapped."

The researchers also discovered that doping was continuously re-activated by the light produced by the device. The light activates the system more, which leads to more light production and more activation until the system is fully activated, Marder said. "This alone is a novel and surprising observation."

The work was supported in part by the National Science Foundation and the U.S. Department of Energy.

Article edited by kynix

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