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Flow Battery Is Increasingly Needed by Electric Power Users

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With the rapid increase in production of intermittent energy sources such as wind and solar, there is an increasing need for large-scale electrical energy storage systems to more efficiently match supply and demand for these renewable sources. Also, large-scale energy storage can increase the annual load factor (defined as the annual mean power divided by the maximum three-day mean power) by load leveling. Traditionally, pumped-hydro has been used for load leveling at large scale plants, but this is geographically limited to a small subset of locations.Flow batteries are especially attractive for these leveling and stabilization applications for electric power companies. In addition, they are also useful for electric power customers such as factories and office buildings that require increased capacities, uninterrupted supply, or backup power.

And how much do you know anything about flow battery?

 

 

Flow Battery

A flow battery is a type of rechargeable battery where rechargeability is provided by two chemical components dissolved in liquids contained within the system and most commonly separated by a membrane. This technology is akin to both a fuel cell and a battery - where liquid energy sources are tapped to create electricity and are able to be recharged within the same system.

 

One of the biggest advantages of flow batteries is that they can be almost instantly recharged by replacing the electrolyte liquid, while simultaneously recovering the spent material for re-energization.

 

Different classes of flow cells (batteries) have been developed, including redox, hybrid and membraneless. The fundamental difference between conventional batteries and flow cells is that energy is stored as the electrode material in conventional batteries but as the electrolyte in flow cells.

 

 

A rechargeable battery to power a home from rooftop solar panels

Recently scientists have said that a rechargeable battery that could make storage of electricity from intermittent energy sources like solar and wind safe and cost-effective for both residential and commercial use. The new research builds on earlier work by members of the same team that could enable cheaper and more reliable electricity storage at the grid level.

 

The mismatch between the availability of intermittent wind or sunshine and the variability of demand is a great obstacle to getting a large fraction of our electricity from renewable sources. This problem could be solved by a cost-effective means of storing large amounts of electrical energy for delivery over the long periods when the wind isn't blowing and the sun isn't shining.

 

In the operation of the battery, electrons are picked up and released by compounds composed of inexpensive, earth-abundant elements (carbon, oxygen, nitrogen, hydrogen, iron and potassium) dissolved in water. The compounds are non-toxic, non-flammable, and widely available, making them safer and cheaper than other battery systems.

 

 

"This is chemistry I'd be happy to put in my basement," says Michael J. Aziz, Gene and Tracy Sykes Professor of Materials and Energy Technologies at Harvard Paulson School of Engineering and Applied Sciences (SEAS), and project Principal Investigator. "The non-toxicity and cheap, abundant materials placed in water solution mean that it's safe—it can't catch on fire—and that's huge when you're storing large amounts of electrical energy anywhere near people."

 

This new rechargeable battery chemistry was discovered by post-doctoral fellow Michael Marshak and graduate student Kaixiang Lin working together with co-lead author Roy Gordon, Thomas Dudley Cabot Professor of Chemistry and Professor of Materials Science at Harvard.

 

"We combined a common organic dye with an inexpensive food additive to increase our battery voltage by about 50 percent over our previous materials," says Gordon. The findings "deliver the first high-performance, non-flammable, non-toxic, non-corrosive, and low-cost chemicals for flow batteries."

 

Unlike solid-electrode batteries, flow batteries store energy in liquids contained in external tanks, similar to fuel cells. The tanks (which set the energy capacity), as well as the electrochemical conversion hardware through which the fluids are pumped (which sets peak power capacity), can be sized independently. Since the amount of energy that can be stored can be arbitrarily increased by scaling up only the size of the tanks, larger amounts of energy can be stored at lower cost than traditional battery systems.

 

 

Application&Benefits

The main benefits of flow batteries can be aggregated into a comprehensive value proposition.The main features that distinguish flow batteries are: 

 

Long service life: The semi-permanent electrolyte combined with minimal electrode degradation allows for a high number of full charge-discharge cycles before replacement is needed. The electrodes do not undergo physical/chemical changes, so they can be optimized for catalytic and electrical properties without having to design for holding active substances. Also, convective cooling of the electrodes by the pumped electrolyte aids in heat distribution and management.

 

No standby loss: During prolonged gaps in use, there is little self-discharge since the charge-carrying electrolyte is stored in separate tanks.

 

Low maintenance: The charge state of each cell is the same since the same electrolyte is used for all cells, thus overcharging is not necessary to guarantee a uniform a charge.

 

Recyclability & Safety: Waste vanadium can be reused and cross-contamination across the positive and negative electrode compartments does not affect the composition. Also, the electrolytes are relatively nontoxic.

 

Charging characteristics: Redox flow batteries are "not affected by fluctuating power demand, repeated total discharge, or charge rates as high as the maximum discharge rates."  These actions severely reduce cycle life in other batteries.

 

Modularity: Perhaps most important is that energy capacity can be scaled independently of the power; cell characteristics such as electrode area do not need to be changed to modify capacity. This allows for underground storage of electrolyte in freeform tanks, which has been demonstrated successfully in a 20 kW system.

 

Ref.

KY605-BP12-12-T2

KY605-EB50-12-I2

 

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